Phosphorous-31 NMR: rules and purposes makes a speciality of the evolution of phosphorus-31 nuclear magnetic resonance (NMR) as a extensively utilized spectroscopic probe of the constitution and dynamics of phosphorus-containing compounds.
The choice first bargains info at the rules and empirical observations of phosphorus-31 chemical shifts and the rules and functions of phosphorus-31 spin-spin coupling constants. Discussions specialize in advent and easy rules, at once bonded phosphorus coupling constants, and two-bond and three-bond coupling constants. The textual content then ponders on phosphorus-31 NMR of enzyme complexes and paramagnetic probes of enzyme complexes with phosphorus-containing compounds.
The manuscript elaborates at the use of chiral thiophosphates and the stereochemistry of enzymatic phosphoryl move and DNA and RNA conformations. subject matters contain helix-coil transitions, series dependence of double-stranded DNA conformations, dynamic habit of RNA and DNA, organic and genetic value, and stereochemical difficulties studied with chiral thiophosphates. The conformation and dynamics of nucleic acids and phosphoproteins, leisure habit of nucleic acids, and idea and purposes of solid-state phosphorus-31 NMR to nucleic acids also are mentioned.
The choice is a worthy reference for readers drawn to the rules and functions of phosphorus-31 nuclear magnetic resonance.